Novel carbon spheres for the treatment of refinery effluents
General Material Designation
[Thesis]
General Material Designation
[Thesis]
General Material Designation
[Thesis]
General Material Designation
[Thesis]
First Statement of Responsibility
Addisu Tadesse Derebe
Subsequent Statement of Responsibility
Wang, Kean
.PUBLICATION, DISTRIBUTION, ETC
Name of Publisher, Distributor, etc.
The Petroleum Institute (United Arab Emirates)
Date of Publication, Distribution, etc.
2014
PHYSICAL DESCRIPTION
Specific Material Designation and Extent of Item
106
GENERAL NOTES
Text of Note
Committee members: Mittal, Vikas; Raj, Abhijeet
NOTES PERTAINING TO PUBLICATION, DISTRIBUTION, ETC.
Text of Note
Place of publication: United States, Ann Arbor; ISBN=978-1-321-32453-2
DISSERTATION (THESIS) NOTE
Dissertation or thesis details and type of degree
M.S.
Discipline of degree
Chemical Engineering
Body granting the degree
The Petroleum Institute (United Arab Emirates)
Text preceding or following the note
2014
SUMMARY OR ABSTRACT
Text of Note
The aim of this thesis is to develop an efficient and low cost adsorbent for refinery wastewater treatment. An environmentally-friendly hydrothermal procedure was employed to synthesize carbon spheres (CS) from glucose solution at 170°C. To study the effect of reaction time, four CS samples were synthesized at 12h, 14h, 16h and 19h. A portion of the samples were surface activated by treatment with 0.5M NaOH, the other portion treated with 0.5M CH3COOH, and the remaining samples were left untreated (native). All samples were characterized using various methods including SEM, XRD, Raman spectroscopy, N2 adsorption and FT-IR. Adsorption experiments of Ag+ and Cu2+ were carried out in batch mode at room temperature. It was found that increasing reaction time resulted in CS with a lower amorphous content and lowered adsorption capacity, NaOH-treated CS had the highest adsorption capacity of 454 mg Ag+/g and 172 mg Cu2+/g, while CH3COOH-treated CS had a lower Ag+ and Cu2+ uptake than untreated CS. The adsorption isotherms were well fit by the Langmuir isotherm equation (for base-treated CS) and the Freundlich isotherm equation (for acid-treated CS). The CS showed a high potential for the removal of heavy-metals from refinery wastewater.